煤炭工程 ›› 2014, Vol. 46 ›› Issue (11): 119-121.doi: 10.11799/ce201411037

• 研究探讨 • 上一篇    下一篇

基于CO浓度的煤低温氧化反应机制实验研究

张平   

  1. 太原理工大学
  • 收稿日期:2014-01-13 修回日期:2014-04-16 出版日期:2014-11-11 发布日期:2014-11-12
  • 通讯作者: 张平 E-mail:tyutzpp311@163.com

Study on the mechanism of coal low-temperature oxidation based on the CO consumption

  • Received:2014-01-13 Revised:2014-04-16 Online:2014-11-11 Published:2014-11-12

摘要:

摘要:CO作为煤自燃过程中的指标气体,对煤自燃状态预测预报具有重要的作用。本文利用实时监测反应装置,模拟采空区遗煤在低温下的氧化过程。根据CO释放速率,对采空区煤的CO释放机制进行分析研究;考察了粒径及初期氧气浓度对CO释放的影响,发现采空区CO释放速率随氧化时间的增加表现出明显的阶段性,并利用数据拟合方法找出CO的产生速率与时间的函数关系式。同时,通过实验对比研究证实,CO的释放速率除了受到氧气浓度和煤体表面活性位点的影响外,主要还是由于煤氧化产生抑制反应的氧化产物。这种机理可以更好地解释采空区遗煤自燃现象。

关键词: 关键词:煤, 低温氧化, CO释放速率, 抑制, 自燃

Abstract:

Abstract: CO, as the index gas in the process of coal spontaneous combustion, plays an important role in forecasting the state of coal spontaneous combustion. In this paper, using the real-time monitoring device, mined-out area of coal oxidation at low temperature oxidation was simulated. The influence of particle size and initial oxygen concentration of CO release, found Gob release CO oxidation time increases performance significantly phased out and use the data fitting method to identify a function of CO production rate versus time style. At the same time, by comparison of the experimental studies have confirmed, CO release rate mainly due to the impact of inhibiting the oxidation reaction product of the reaction of oxygen in the coal besides the oxygen concentration and the surface active sites of the coal, such a mechanism may be better to explain the phenomenon of spontaneous combustion of coal.

Key words: Keywords: coal, low-temperature oxidation, the rate of CO release, prevention, Spontaneous combustion